MATERIAL SAFETY DATA SHEET
Printed: May 05, 2008 09:50:35
Product #: 705 CITRONELLOL BRI FCC
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Bedoukian Research, Inc. Emergency Phone Numbers:
21 Finance Drive 1-800-424-9300 Chemtrec (North America)
Danbury, CT 06810-4192 1-703-527-3887 Chemtrec (International)
UNITED STATES
Phone: 1-203-830-4000
Product Code: 705
Product Name: CITRONELLOL BRI FCC
Last Revision: May 05, 2008
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SECTION 2. HAZARDS IDENTIFICATION
HMIS HAZARD CLASSIFICATIONS
HEALTH = 1 FLAMMABILITY = 1 REACTIVITY = 0 PROTECTION = B
LABEL PRECAUTIONARY STATEMENTS
U.S. HAZARD LABELING
Skin irritant.
EUROPEAN SYMBOLS
Irritant
EUROPEAN R PHRASES
Irritating to skin.
May cause sensitization by skin contact.
EUROPEAN S PHRASES
Avoid contact with skin.
Wear suitable gloves.
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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS #: 106-22-9
FEMA #: 2309 COE #: 59
MF: C10H20O
EC NO: 203-375-0
SYNONYM(S)
6-Octen-1-ol, 3,7-dimethyl-
2,3-Dihydrogeraniol
2,6-Dimethyl-2-octen-8-ol
3,7-Dimethyl-6-octen-1-ol
3,7-Dimethyloct-6-en-1-ol
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SECTION 4. FIRST-AID MEASURES
INHALATION EXPOSURE: Remove to fresh air. Give oxygen and call a physician.
EYE CONTACT: Flush with water for 15 min. Seek medical help if necessary.
SKIN CONTACT: Wash area well with water. Seek medical help if necessary.
INGESTION: Administer water and call a physician or poison control
center immediately. Do not induce vomiting.
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SECTION 5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
CO2, FOAM, DRY CHEMICAL
SPECIAL FIRE FIGHTING PROCEDURES
Use standard fire fighting procedures.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None.
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SECTION 6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Standard absorbents can be used.
WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
accordance with local, state, and federal regulations.
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SECTION 7. HANDLING AND STORAGE
HANDLING
Observe all warnings and precautions listed for the product.
Use in accordance with good manufacturing and industrial
hygiene practices. Use product in a properly ventilated work
area. Do not eat, drink or smoke while handling product.
STORAGE
Store tightly sealed under inert gas in a cool, well-ventilated area.
FIRE PROTECTION
Keep away from heat, sparks, and open flame.
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Local exhaust preferred. General ventilation required.
RESPIRATORY: Usually not required. Avoid inhaling concentrated vapors.
SKIN: Avoid skin contact. Use chemical resistant gloves.
EYES: Splash-proof safety glasses or goggles.
OTHER PROTECTIVE EQUIPMENT: Safety shower, eye wash
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
APPEARANCE: colorless liquid
ODOR DESCRIPTION: fresh, clean, floral rosy odor.
BOILING POINT: 90C @ 0.1 mm Hg
VAPOR PRESSURE : 0.009 mmHg @ 20 C
VAPOR DENSITY (Air = 1): > 1
SPECIFIC GRAVITY @ 25C (water = 1): 0.8500:0.8600
SOLUBILITY IN WATER: Insoluble in water; soluble in alcohol.
FLASH POINT (CC): 210 F 98 C
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SECTION 10. STABILITY AND REACTIVITY
INCOMPATIBILITIES
CONDITIONS TO AVOID: Presents no special reactivity hazard.
MATERIALS TO AVOID: Strong oxidizing agents
HAZARDOUS COMBUSTION PRODUCTS
CO, CO2, water
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SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE EFFECTS
Most likely route of entry is through the skin.
Full strength may be irritating to skin and eyes.
IFRA RECOMMENDATIONS
There is an IFRA guideline regarding this product. Visit www.ifraorg.org
for the full text of the guideline, or contact Bedoukian Research, Inc.
for more information.
The following restrictions apply for Citronellol & its isomers: In finished
products: C01=0.8%; C02=1.1%; C03=4.4%; C04=13.3%; C05=7.0%; C06=21.4%;
C07=2.2%; C08=2.0%; C09=5.0%; C10=2.5%; C11=The concn. of Citronellol and
its isomers should not exceed the usual concn. of fragrance compd. in the
finished pdt.
RTECS NUMBERS
RTECS: (6-Octen-1-ol, 3,7-dimethyl-) RH3400000
IRRITATION DATA
4% in petrolatum produced no irritation or sensitization in humans.
TOXICITY DATA
LD50 Dermal (rabbit) 2.65 g/kg.
LD50 Oral (rat) 3.45 g/kg.
THRESHOLD LIMIT VALUE (TLV): Not established
OSHA PERMISSABLE EXPOSURE LIMIT (PEL): Not established
LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?: NO
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SECTION 12. ECOLOGICAL INFORMATION
GENERAL
Prevent contamination of soil, ground- and surface water.
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SECTION 13. DISPOSAL CONSIDERATION
WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
accordance with local, state, and federal regulations.
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SECTION 14. TRANSPORT INFORMATION
Class Pack Group Sub. Risk UN No.
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Road(U.S.-DOT): not regulated.
Air (IATA): not regulated.
Sea (IMDG): not regulated.
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SECTION 15. REGULATORY INFORMATION
EUROPEAN INFORMATION
Irritant
The following risk and safety phrases were assigned based on toxicological
studies in the published literature:
R38
Irritating to skin.
R43
May cause sensitization by skin contact.
S24
Avoid contact with skin.
S37
Wear suitable gloves.
REVIEWS, STANDARDS, AND REGULATIONS
This chemical is listed on the following inventories:
TSCA AICS CHINA DSL ECL EINECS(203-375-0) ENCS PICCS SWISS
LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?: NO
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SECTION 16. OTHER INFORMATION
DISCLAIMER OF WARRANTIES AND LIMITATION OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH
WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED
WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED REGARDING ITS CORRECTNESS.
BEDOUKIAN RESEARCH INC. ("BRI") MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE WITH RESPECT TO THE
INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
BRI'S SOLE AND EXCLUSIVE LIABILITY WITH RESPECT TO PRODUCTS
PROVIDED TO BRI'S SATISFACTION TO BE DEFECTIVE OR NONCONFORMING
SHALL BE THE REPLACEMENT OF SUCH PRODUCTS WITHOUT CHARGE OR REFUND
OF THE PURCHASE PRICE UPON THE RETURN OF SUCH PRODUCTS IN ACCORDANCE
WITH BRI'S INSTRUCTIONS. THIS REMEDY, IN THE MANNER PROVIDED HEREIN,
SHALL CONSTITUTE FULFILLMENT OF ALL LIABILITIES OF BRI, WHETHER BASED
ON CONTRACT, TORT OR OTHERWISE WITH RESPECT TO, OR ARISING OUT OF THE
PRODUCTS. BRI SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL,
CONTINGENT OR SPECIAL DAMAGES.
