MATERIAL SAFETY DATA SHEET
Printed: Aug 10, 2009 14:54:00
Product #: 426 PHENYL ETHYL TIGLATE
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Bedoukian Research, Inc. Emergency Phone Numbers:
21 Finance Drive 1-800-424-9300 Chemtrec (North America)
Danbury, CT 06810-4192 1-703-527-3887 Chemtrec (International)
UNITED STATES
Phone: 1-203-830-4000
Product Code: 426
Product Name: PHENYL ETHYL TIGLATE
Last Revision: Aug 10, 2009
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SECTION 2. HAZARDS IDENTIFICATION
HMIS HAZARD CLASSIFICATIONS
HEALTH = 1 FLAMMABILITY = 1 REACTIVITY = 0 PROTECTION = B
LABEL PRECAUTIONARY STATEMENTS
U.S. HAZARD LABELING
May be irritating to skin and eyes.
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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS #: 55719-85-2
FEMA #: 2870 COE #: 2186
MF: C13H16O2
EC NO: 259-774-5
SYNONYM(S)
2-Butenoic acid, 2-methyl-, 2-phenylethyl ester, (2E)-
2-Phenylethyl tiglate
2-Phenylethyl trans-2,3-dimethylacrylate
Benzylcarbinyl tiglate
Phenethyl 2-methylcrotonate
Phenethyl tiglate
Phenylethyl tiglate
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SECTION 4. FIRST-AID MEASURES
INHALATION EXPOSURE: Remove to fresh air. Give oxygen and call a physician.
EYE CONTACT: Flush with water for 15 min. Seek medical help if necessary.
SKIN CONTACT: Wash area well with water. Seek medical help if necessary.
INGESTION: Administer water and call a physician or poison control
center immediately. Do not induce vomiting.
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SECTION 5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
CO2, FOAM, DRY CHEMICAL, WATER FOG
SPECIAL FIRE FIGHTING PROCEDURES
Use standard fier fighting procedures.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None.
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SECTION 6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Standard absorbents can be used.
WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
accordance with local, state, and federal regulations.
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SECTION 7. HANDLING AND STORAGE
HANDLING
Observe all warnings and precautions listed for the product.
Use in accordance with good manufacturing and industrial
hygiene practices. Use product in a properly ventilated work
area. Do not eat, drink or smoke while handling product.
STORAGE
Store tightly sealed under inert gas in a cool, well-ventilated area.
FIRE PROTECTION
Keep away from heat, sparks, and open flame.
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Local exhaust preferred. General ventilation required.
RESPIRATORY: Usually not required. Avoid inhaling concentrated vapors.
SKIN: Avoid skin contact. Use chemical resistant gloves.
EYES: Splash-proof safety glasses or goggles.
OTHER PROTECTIVE EQUIPMENT: Safety shower, eye wash
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
APPEARANCE: colorless liquid
ODOR DESCRIPTION: heavy rose note.
BOILING POINT: 125C @ < 0.1 mm Hg
VAPOR PRESSURE : 0.002 mmHg @ 20 C
VAPOR DENSITY (Air = 1): > 1
SPECIFIC GRAVITY @ 25C (water = 1): 1.0104:1.0170
SOLUBILITY IN WATER: Almost insoluble in water.
FLASH POINT (CC): 215 F 101 C
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SECTION 10. STABILITY AND REACTIVITY
INCOMPATIBILITIES
CONDITIONS TO AVOID: Presents no special reactivity hazard.
MATERIALS TO AVOID: Strong oxidizing agents
HAZARDOUS COMBUSTION PRODUCTS
CO, CO2, water
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SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE EFFECTS
Most likely route of entry is through the skin.
Full strength may be irritating to skin and eyes.
RTECS NUMBERS
RTECS: (2-Butenoic acid, 2-methyl-, phenethyl ester) EM9255000
IRRITATION DATA
6% in petrolatum produced no irritation in humans.
TOXICITY DATA
LD50 Dermal (rabbit) > 5 g/kg.
LD50 Oral (rat) > 5 g/kg.
OTHER DATA
6% in petrolatum produced no sensitization in humans.
THRESHOLD LIMIT VALUE (TLV): Not established
OSHA PERMISSABLE EXPOSURE LIMIT (PEL): Not established
LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?: NO
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SECTION 12. ECOLOGICAL INFORMATION
GENERAL
Prevent contamination of soil, ground- and surface water.
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SECTION 13. DISPOSAL CONSIDERATION
WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
accordance with local, state, and federal regulations.
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SECTION 14. TRANSPORT INFORMATION
Class Pack Group Sub. Risk UN No.
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Road(U.S.-DOT): not regulated.
Air (IATA): not regulated.
Sea (IMDG): not regulated.
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SECTION 15. REGULATORY INFORMATION
EUROPEAN INFORMATION
Based on toxicological studies in the published literature, there are no
risk and safety phrases to assign for this product.
REVIEWS, STANDARDS, AND REGULATIONS
This chemical is listed on the following inventories:
TSCA AICS CHINA DSL EINECS(259-774-5) ENCS PICCS
LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?: NO
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SECTION 16. OTHER INFORMATION
DISCLAIMER OF WARRANTIES AND LIMITATION OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH
WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED
WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED REGARDING ITS CORRECTNESS.
BEDOUKIAN RESEARCH INC. ("BRI") MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE WITH RESPECT TO THE
INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
BRI'S SOLE AND EXCLUSIVE LIABILITY WITH RESPECT TO PRODUCTS
PROVIDED TO BRI'S SATISFACTION TO BE DEFECTIVE OR NONCONFORMING
SHALL BE THE REPLACEMENT OF SUCH PRODUCTS WITHOUT CHARGE OR REFUND
OF THE PURCHASE PRICE UPON THE RETURN OF SUCH PRODUCTS IN ACCORDANCE
WITH BRI'S INSTRUCTIONS. THIS REMEDY, IN THE MANNER PROVIDED HEREIN,
SHALL CONSTITUTE FULFILLMENT OF ALL LIABILITIES OF BRI, WHETHER BASED
ON CONTRACT, TORT OR OTHERWISE WITH RESPECT TO, OR ARISING OUT OF THE
PRODUCTS. BRI SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL,
CONTINGENT OR SPECIAL DAMAGES.
